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| Recall that in QM: <math>\ L = \hbar\sqrt{l(l+1)}</math>; <math>\ L_z = m\hbar</math>.
| | In quantum mechanics, |
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| The angle <math>\ \theta </math> between <math> \mathbf{L} </math> and the z-axis fulfills: <math>\ \cos \theta = \frac{L_z}{L} = \frac{m}{\sqrt{l(l+1)}}</math>.
| | <math>L=\sqrt{\langle\hat{\mathbf{L}}^2\rangle}=\hbar\sqrt{l(l+1)}</math> |
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| To make <math>\ \theta </math> as small as possible, <math>\ m </math> must be maximum (<math>\ l </math> is fixed in this problem). This is when <math>\ m=l </math>.
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| Therefore, the minimum angle <math>\ \alpha </math> obeys: <math>\ \cos \alpha = \frac{l}{\sqrt{l(l+1)}} </math>
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| We solve <math>\ L = \hbar\sqrt{l(l+1)}</math> to find <math>\ l </math>.
| | <math>L_z=\langle\hat{L}_z\rangle=m\hbar.</math> |
| Since <math>\ l </math> will be very large we invoke the approximation: <math>\ \sqrt{l(l+1)} \approx l \sqrt{\left(1+\frac{1}{l}\right)} = l+\frac{1}{2}</math>. We resist the urge to discard the <math> \frac{1}{2} </math> because without it our result will be trivial.
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| <math>\ L= \hbar\left(l+\frac{1}{2}\right)</math>. Therefore <math>\ l = \frac{L}{\hbar}-\frac{1}{2}</math>. Plugging this expression into the equation for <math>\ \alpha </math> and using the previous approximation again, we have: <math>\ \cos \alpha \approx \frac{l}{l+\frac{1}{2}} = \frac{\frac{L}{\hbar}-\frac{1}{2}}{\frac{L}{\hbar}} = \frac{2L-\hbar}{2L}</math>.
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| <math>\ \alpha \approx cos^{-1}\frac{2L-\hbar}{2L}</math>. | | The angle <math>\theta</math> between <math>\mathbf{L}</math> and the <math>z\!</math> axis is given by |
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| Plugging in <math>\ L = 4.83 \cdot 10^{31} J \cdot s </math> and <math>\ \hbar = 1.055 \cdot 10^{-34} J \cdot s</math> we obtain:
| | <math>\cos{\theta}= \frac{L_z}{L} = \frac{m}{\sqrt{l(l+1)}}.</math> |
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| | To make <math>\theta </math> as small as possible, <math>m\!</math> must be at its maximum value, <math>m=l.\!</math> |
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| | Therefore, the minimum angle <math>\theta=\alpha\!</math> is given by |
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| <math>\ \alpha \approx cos^{-1}(0.999999999999999999999999999999999999999999999999999999999999999998908) \approx 1.48 \cdot 10^{-33} rad</math>. | | <math>\cos{\alpha}=\frac{l}{\sqrt{l(l+1)}},</math> |
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| This is the smallest angle that <math>\ \mathbf{L} </math> can make with the z-axis in the case of the earth going around the sun.
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| | <math>\sin{\alpha}=\frac{1}{\sqrt{l+1}}.</math> |
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| In the case of a quantum particle with <math>\ l = 4</math>, we must use the exact expression: <math>\ \cos \alpha = \frac{l}{\sqrt{l(l+1)}} </math>.
| | We now solve <math>\ L = \hbar\sqrt{l(l+1)}</math> to find <math>l.\!</math> |
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| <math>\ \cos \alpha = \frac{4}{\sqrt{4(4+1)}} = \frac{4}{\sqrt{4(4+1)}} = \frac{4}{\sqrt{20}} = \frac{2}{\sqrt{5}}</math>. | | Since <math>\ l</math> will be very large, we make the approximation, <math>\ \sqrt{l(l+1)} \approx l \sqrt{\left(1+\frac{1}{l}\right)} = l,</math> so that <math>L\approx l\hbar.</math> Because <math>l\!</math> is large, we see that <math>\sin{\alpha}</math> is small, and thus we may make the approximation, |
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| <math>\ \alpha \approx 0.464 rad \approx 26.6 \deg </math>. | | <math>\alpha\approx\sqrt{\frac{\hbar}{L}}.</math> |
| This is the smallest angle that the angular momentum vector of a particle with <math>\ l=4 </math> can make with the z-axis.
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| Back to [[Orbital Angular Momentum Eigenfunctions]] | | If we now substitute in <math>\ L = 4.83\times 10^{31}\,\text{J}\cdot\text{s}</math> and <math>\ \hbar = 1.055 \times 10^{-34}\,\text{J} \cdot \text{s},</math> we obtain |
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| | <math>\ \alpha \approx \sqrt{\frac{1.055\times 10^{-34}}{4.83\times 10^{31}}}\approx 1.48 \times 10^{-33}\,\text{rad}.</math> |
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| | This is the smallest angle that <math>\mathbf{L}</math> can make with the <math>z\!</math> axis in the case of the Earth going around the sun. |
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| | In the case of a quantum particle with <math>\ l = 4</math>, we must use the exact expression for the angle. |
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| | <math>\ \sin \alpha = \frac{1}{\sqrt{5}},</math> |
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| | which gives us |
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| | <math>\ \alpha \approx 0.464\,\text{rad} = 26.6 \deg. </math> |
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| | This is the smallest angle that the angular momentum vector of a particle with <math>\ l=4 </math> can make with the <math>z\!</math> axis. This angle is much larger than that for the Earth orbiting the sun, as we would expect. |
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| | Back to [[Orbital Angular Momentum Eigenfunctions#Problems|Orbital Angular Momentum Eigenfunctions]] |
Latest revision as of 13:40, 18 January 2014
In quantum mechanics,
and
The angle 
between 
and the 
axis is given by
To make as small as possible, 
must be at its maximum value, 
Therefore, the minimum angle 
is given by
or by
We now solve 
to find 
Since 
will be very large, we make the approximation, 
so that 
Because 
is large, we see that 
is small, and thus we may make the approximation,
If we now substitute in 
and 
we obtain
This is the smallest angle that can make with the axis in the case of the Earth going around the sun.
In the case of a quantum particle with 
, we must use the exact expression for the angle.
which gives us
This is the smallest angle that the angular momentum vector of a particle with can make with the axis. This angle is much larger than that for the Earth orbiting the sun, as we would expect.
Back to Orbital Angular Momentum Eigenfunctions