Phy5645/Problem 1D sample

(Submitted by team 1. Based on problem 3.19 in Schaum's Theory and problems of Quantum Mechanics)

Consider a particle of mass m in a three dimensional potential: $V(x,y,z)=X(x)+Y(y)+Z(z)\!$

Using the Schroedinger's equation show that we can treat the problem like three independent one-dimensional problems. Relate the energy of the three-dimensional state to the effective energies of one-dimensional problem.

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The Schroedinger's equation takes the form:

$-{\frac {\hbar ^{2}}{2m}}{\frac {d^{2}\psi (x,y,z)}{dx^{2}}}+\left(X(x)+Y(y)+Z(z)\right)\psi (x,y,z)=E\psi (x,y,z)$

Assuming that $\psi \!$ can be write like:

$\psi (x,y,z)=\Phi (x)\Delta (y)\Omega (z)\!$

So,

${\begin{aligned}-{\frac {\hbar ^{2}}{2m}}\left[{\frac {d^{2}\Phi (x)}{dx^{2}}}\Delta (y)\Omega (z)+\Phi (x){\frac {d^{2}\Delta (y)}{dy^{2}}}\Omega (z)+\Phi (x)\Delta (y){\frac {d^{2}\Omega (z)}{dz^{2}}}\right]\\+\left[X(x)+Y(y)+Z(z)\right]\Phi (x)\Delta (y)\Omega (z)=E\Phi (x)\Delta (y)\Omega (z)\end{aligned}}$

Dividing by $\psi (x,y,z)\!$

${\begin{aligned}-{\frac {\hbar ^{2}}{2m}}{\frac {1}{\Phi (x)}}{\frac {d^{2}\Phi (x)}{dx^{2}}}+X(x)-{\frac {\hbar ^{2}}{2m}}{\frac {1}{\Delta (y)}}{\frac {d^{2}\Delta (y)}{dy^{2}}}+Y(y)\\-{\frac {\hbar ^{2}}{2m}}{\frac {1}{\Omega (z)}}{\frac {d^{2}\Omega (z)}{dz^{2}}}+Z(z)=E\end{aligned}}$

Perfectly we can separate the right hand side in three parts, where only one depends of $x\!$, only one of $y\!$ and only one of $z\!$. Then each of these parts must be equal to a constant. So:

$-{\frac {\hbar ^{2}}{2m}}{\frac {1}{\Phi (x)}}{\frac {d^{2}\Phi (x)}{dx^{2}}}+X(x)=E_{x}$

$-{\frac {\hbar ^{2}}{2m}}{\frac {1}{\Delta (y)}}{\frac {d^{2}\Delta (y)}{dy^{2}}}+Y(y)=E_{y}$

$-{\frac {\hbar ^{2}}{2m}}{\frac {1}{\Omega (z)}}{\frac {d^{2}\Omega (z)}{dz^{2}}}+Z(z)=E_{z}$

where $E_{x}\!$, $E_{y}\!$ and $E_{z}\!$ are constant and $E=E_{x}+E_{y}+E_{z}\!$

Hence the three-dimensional problem has been divided in three one-dimensional problems where the total energy $E\!$ is the sum of the energies $E_{x}\!$, $E_{y}\!$ and $E_{z}\!$ in each dimension.