Phy5646/Non-degenerate Perturbation Theory - Problem 3

(Submitted by Team 1)

This example taken from "Quantum Physics" 3rd ed., Stephen Gasiorowicz, p. 177.

Problem: A charged particle in a simple harmonic oscillator, for which ${H}_{0}={\frac {p^{2}}{2m}}+{\frac {mw^{2}}{2}}$, subject to a constant electric field so that ${H}^{'}=q{\mathcal {E}}x$. Calculate the energy shift for the $n^{th}$ level to first and second order in $(q{\mathcal {E}})$. (Hint: Use the operators $a$ and $a^{\dagger }$ for the evaluation of the matrix elements).

Solution: (a) To first order we need to calculate ${H}^{'}=q{\mathcal {E}}\langle n|x|n\rangle$. It is easy to show that (n[x|n) = 0. One way is to use the relation (7-4), from which we get h (A + A+) 2mio and since A\n) = \fn\n — 1) and A+\n) = Vn + \\n + 1) we see that («|jc|«) = 0. Another way of seeing this is that the matrix element involves the integral CO CO J 0*(*W>„(jc) = J dxx\$n(x)\2 Since |</>„(jt)|2 is always an even function of x (</>„(— x) = (— l)"<£„(jt)), the integral from — °= to +» involving an odd integrand is zero. (b) The second-order term involves a^y \{k\x\n)\2 _q2%2 h \(k\A+A+\n)\2 ten hm(n — k) fuo 2mio ^n n — k The only contributions come from k = n — 1 and k = n + 1, so that \{k\A + A+\n)\2 _ |V^|2 | |V^TI|2 _ i ten n-k 1 -1 and thus 9¾2 £(2) = 2mu> The result is independent of n. We can check for its correctness by noting that the total potential energy is 1 n co 1 J ? 24% \ I i( <&> Y 92¾2 — rruo x + q%x = ■= m<o\ xr H x I = -z ma>\ x H 2 H 2 \ tm? I 2 V mco2/ 2rm>2 Thus the perturbation shifts the center of the potential by —q%/mco2 and lowers the energy by q2%2l2rmp-, which agrees with our second-order result.