PHZ3400 Sound

Vibrational modes of a one-dimensional chain

Harmonic approximation: inter-atomic forces as springs

• If we put energy into a crystal the atoms will begin to vibrate.
• We are able to put energy into the crystal in two ways: Mechanical and Thermal.
  • Mechanical energy are sound waves
  • Thermal energy can be used to measure resistivity.
• Periodicity helps to simplify the problem of lattice vibrations.
• One atom moves with the frequency $\omega _{0}={\sqrt {\frac {k}{m}}}$
  • If we have many atoms moving together than they effectively have a larger mass, therefore they will have a smaller frequency.
• Broken Symmetry
• Collective Phenomenon - behavior changes when in a large group

$H_{2}$ Example

Consider an $H_{2}$ molecule. Assume one is at rest while the other moves. $ma=-{\frac {dV(r)}{dt}}$

,where $V$ is potential energy and $r$ is radius. This can be rewritten as

$m{\frac {d^{2}r}{dt^{2}}}=-{\frac {dV(r)}{dt}}$

This equation cannot be solved via conventional methods, so we must somehow simplify it. Let us only worry about very small oscillations. This reduces our problem to a harmonic oscillator. Small oscillations can be described simply since it is parabolic at the minimum energy.

Now we expand $V(r)$ in Taylor Series (note $r_{0}$ is the radius with minimum V)

$V(r)=V(r_{0})+V'(r_{0})(r-r_{0})+{\frac {1}{2}}K(r-r_{0})^{2}$

,where $K={\frac {d^{2}V}{dt^{2}}}$.Notice that the second term is the derivative of $V$ at $r_{0}$, which is a minimum, therefore the derivative is zero and this term can be ignored. Now we have

$V(r)=V(r_{0})+{\frac {1}{2}}K(r-r_{0})^{2}$

Now let $u=(r-r_{0})$ and we have

$V(u)=V_{0}+{\frac {1}{2}}Ku^{2}$ and ${\frac {dV(u)}{du}}=Ku$

...

$\Rightarrow -\omega ^{2}u=-{\frac {k}{m}}u$

$\Rightarrow \omega ={\sqrt {\frac {k}{m}}}$

Two Atom Model

• Corresponds to putting $H_{2}$ in a potential well

• We can reduce this problem to particles on springs

• Solve via eigenvalue analysis

• Two Modes
  • Both Particles move in concert
  • Both Particles move opposite to each other

• If one of these particles are displaced (ignore the effects of the second) it will act as a linear Harmonic Oscillator, so that it will act as a simple sine wave.
  • However, if you take into account the second particle, the problem will not be so simple since there will be a superposition of two since waves creating a beat pattern. If the displacement is described by one of the modes above then there will be a simple sine wave.

We can write the equations of motion for these two particles as

$m{\ddot {u}}_{1}=-ku_{1}-k(u_{1}-u_{2})\!$

$m{\ddot {u}}_{2}=-ku_{2}-k(u_{2}-u_{1})\!$

,where $k$ is the spring constant, $m$ is mass, and $u$ is displacement from the particles equilibrium position. We can rewrite these equations as

$m{\ddot {u}}_{1}=-2ku_{1}+ku_{2}\!$

$m{\ddot {u}}_{2}=ku_{1}-2ku_{2}\!$

Or

$m{\ddot {u}}_{1}+2ku_{1}-ku_{2}=0\!$

$m{\ddot {u}}_{2}-ku_{1}+2ku_{2}=0\!$

We can create a matrix representation for this system of equations by letting

${\overrightarrow {u}}={\begin{bmatrix}u_{1}\\u_{2}\end{bmatrix}}$

So, we have

Failed to parse (unknown function "\begin{bmatrix}"): {\displaystyle k\begin{bmatrix} 2 & -1 \\ -1 & 2\end{bmatrix} \begin{bmatrix} u_1 \\ u_2 \end = 0{bmatrix}}