Oscillation Theorem

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Quantum Mechanics A
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Schrödinger Equation
The most fundamental equation of quantum mechanics; given a Hamiltonian , it describes how a state evolves in time.
Basic Concepts and Theory of Motion
UV Catastrophe (Black-Body Radiation)
Photoelectric Effect
Stability of Matter
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Oscillation Theorem
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Let be a bound state of a given potential with energy and be another bound state with energy such that . Let be a point at which both and vanish; this is guaranteed to happen at least for We will now prove that, between any two points and at which vanishes, there must be at least one point at which vanishes. Let us begin by writing down the Schrödinger equation for each wave function:

Multiplying the first equation by and the second by subtracting the second equation from the first, and simplifying, we see that

If we now integrate both sides of this equation from to any position and simplify, we see that

The key is to now let be the first position to the right of where vanishes.

Now, if we assume that does not vanish at or between and , then it is easy to see that the left hand side of the previous equation has a different sign from that of the right hand side, and thus it must be true that must vanish at least once between and if