The Dirac Delta Function Potential

Quantum Mechanics A

Schrödinger Equation The most fundamental equation of quantum mechanics; given a Hamiltonian ${\mathcal {H}}$, it describes how a state $|\Psi \rangle$ evolves in time.

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A delta function potential, $V(x)=V_{0}\delta (x-a)\!$, is a special case of the symmetric finite square well; it is the limit in which the width of the well goes to zero and the depth of the well goes to infinity, while the product of the height and depth remains constant. For such a potential, the wave function is still continuous across the potential, ie. $x=a\!$. However, the first derivative of the wave function is not.

For a particle subject to an attractive delta function potential, $V(x)=-V_{0}\delta (x),\!$ the Schrödinger equation is

$-{\frac {\hbar ^{2}}{2m}}{\frac {d^{2}\psi (x)}{dx^{2}}}-V_{0}\delta (x)\psi (x)=E\psi (x).$

For $x\neq \!0$ the potential term vanishes, and all that is left is

${\frac {d^{2}\psi (x)}{dx^{2}}}+{\frac {2mE}{\hbar ^{2}}}\psi (x)=0.$

One or more bound states may exist, for which $E<0\!$, and $\psi (x)\!$ vanishes at $x=\pm \infty \!$. The bound state solutions are given by

$\psi _{I}(x)=Ae^{kx},\,x<0\!$

$\psi _{II}(x)=Be^{-kx},\,x>0\!$

where $k={\frac {\sqrt {-2mE}}{\hbar }}.$

The first boundary condition, the continuity of $\psi (x)\!$ at $x=0\!$, yields $A=B\!$.

The second boundary condition, the discontinuity of ${\frac {d\psi (x)}{dx}}\!$ at $x=0\!$, can be obtained by integrating the Schrödinger equation from $-\epsilon \!$ to $\epsilon \!$ and then letting $\epsilon \rightarrow 0\!$

Integrating the whole equation across the potential gives

$-{\frac {\hbar ^{2}}{2m}}\int _{-\epsilon }^{\epsilon }{\frac {d^{2}\psi (x)}{dx^{2}}}dx+\int _{-\epsilon }^{+\epsilon }(-V_{0}\delta (x))\psi (x)dx=\int _{-\epsilon }^{\epsilon }E\psi (x)dx$

In the limit $\epsilon \rightarrow 0\!$, we have

$-{\frac {\hbar ^{2}}{2m}}\left[{\frac {d\psi _{II}(0)}{dx}}-{\frac {d\psi _{I}(0)}{dx}}\right]-V_{0}\psi (0)=0,$

which yields the relation, $k={\frac {mV_{0}}{\hbar ^{2}}}.\!$.

Since we defined $k={\frac {\sqrt {-2mE}}{\hbar }},\!$, we have ${\frac {\sqrt {-2mE}}{\hbar }}={\frac {mV_{0}}{\hbar ^{2}}}\!$. Then, the energy is Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle E = -\frac{mV_0^2}{2\hbar^2} \!}

Finally, we normalize Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \psi(x) \!} :

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \int_{-\infty}^{\infty} |\psi(x)|dx=2|B|^2\int_{0}^{\infty} e^{-2kx}dx=\frac{|B|^2}{k}=1 }

so,

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle B=\sqrt{k}=\frac{\sqrt{mV_{0}}}{\hbar} }

Evidently, the delta function well, regardless of its "strength" Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle V_{0} \!} , has one bound state:

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \psi(x)=\frac{\sqrt{mV_{0}}}{\hbar}e^{\frac{-mV_{0}|x|}{\hbar^{2}}} }

Similarly, for a delta potential of the form Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle V_0\delta(x-a)\!} , the discontinuity of the first derivative can be shown as follows:

The Schrödinger equation is

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle -\frac{\hbar^2}{2m}\frac{d^2 \psi(x)}{dx^2}+V_0\delta(x-a)\psi(x)=E\psi(x)}

Integrating the whole equation across the potential gives

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle -\frac{\hbar^2}{2m}\int_{a-\epsilon}^{a+\epsilon} \frac{d^2 \psi(x)}{dx^2}dx+\int_{a-\epsilon}^{a+\epsilon} V_0\delta(x-a)\psi(x)dx=\int_{a-\epsilon}^{a+\epsilon} E \psi(x)dx}

In the limit Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \epsilon \rightarrow 0 \!} , we have

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle -\frac{\hbar^2}{2m}\left[\frac{d \psi(a^+)}{dx}-\frac{d \psi(a^-)}{dx}\right]+V_0\psi(a)=0}

Hence the first derivative of the wave function across a delta potential is discontinuous by an amount:

Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \frac{d \psi(a^+)}{dx}-\frac{d \psi(a^-)}{dx}=\frac{2m V_0}{\hbar^2}\psi(a)}

Problem

(Double delta function potential)

Consider the double delta function potential, Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle V(x)=-g\delta(x-a)–g\delta(x+a).} Prove that a ground state with even parity always exists. By means of a sketch, show that a first excited state also exists for a sufficiently large well separation Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle 2a.}

Solution

External Link

Additional information on the dirac delta function